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Studies on Structure Reactivity Correlation in some Organoredox Reactions

Shailendra, M. B. Ojha, Arun Kumar Mishra, Shashi Kant Yadav, R. J. Bhatt and M. K. Bhatt

Ortho and para substituted derivatives of piperidin-4-one have been prepared using the path suggested by Mannich reaction, in which different electron withdrawing and releasing groups were introduced. These compounds were oxidized by N-bromosuccinimide and the kinetics and mechanism of reactions have been calculated, compared and analysed. The study of comparative rates of oxidation of these compounds reflects the conclusions about the position and nature of the groups in the structure of compounds, which influence the nature of the groups in the structure of compounds and reactivity of oxidation.